Zirconium (IV) chloride, e tsejoang hape e lezirconium tetrachloride, e na le foromo ea molek'hule ZrCl4 le boima ba molek'hule ea 233.04.Haholo-holo e sebelisoa e le li-reagents tsa tlhahlobo, li-catalysts tsa organic synthesis, liente tse thibelang metsi, lisebelisoa tsa ho suha matlalo.
Lebitso la sehlahisoa:Zirconium chloridelihlahisoa tsa zirconium tetrachloride;Zirconium (IV) chloride
Boima ba molek'hule: 233.04
EINECS : 233-058-2
Sebaka se belang: 331 (sublimation)
Boima:2.8
Foromo ea lik'hemik'hale:ZrCl4
CAS :10026-11-6
Sebaka se qhibilihang: 437
Ho qhibiliha ha metsi: Ho qhibiliha ka metsing a batang
1.Mehaho
Lintho tsa 'mele le tsa lik'hemik'hale
1. Sebopeho: Klastale e benyang e tšoeu kapa phofo, e botsoa habonolo.
2. Sebaka se qhibilihang (℃): 437 (2533.3kPa)
3. Sebaka se belang (℃): 331 (sublimation)
4. Boima ba kamano (metsi=1): 2.80
5. Khatello ea mouoane (kPa): 0.13 (190 ℃)
6. Khatello e boima (MPa): 5,77
7. Ho qhibiliha: Ho qhibiliha metsing a batang, ethanol, le ether, e sa qhibiliheng ka har'a benzene, carbon tetrachloride, le carbon disulfide.
Ho bonolo ho monya mongobo le mongobo, ho kenngoa ka hydrolyzed ka hydrogen chloride le zirconium oxychloride moeeng o mongobo kapa tharollo ea metsi, equation e tjena:
Botsitso
1. Botsitso: E tsitsitseng
2. Lintho tse hanetsoeng: metsi, liamine, joala, acid, ester, ketone.
3. Maemo a ho qoba ho kopana: moea o mongobo
4. Kotsi ea polymerization: eseng polymerization
5. Sehlahisoa sa ho bola: chloride
2.Tlhahiso
(1) E sebelisetsoa ho etsa zirconium ea tšepe, li-pigments, masela a thibelang metsi, lisebelisoa tsa ho etsa letlalo la letlalo, joalo-joalo.
(2) E sebelisoa bakeng sa tlhahiso ea metsoako ea zirconium le metsoako ea organic metal organic, e ka sebelisoa e le solvent le e hloekisang bakeng sa tšepe ea magnesium e qhibilihisitsoeng, e nang le liphello tsa ho tlosa tšepe le silicon.
3.Mokhoa oa maiketsetso
Beha boima ba zirconia le calcined carbon black ho ea ka tekanyo ea molar ea tekanyo, kopanya ka ho lekana 'me u li behe ka seketsoaneng sa porcelain.Beha seketsoana sa porcelain ka har'a tube ea porcelain 'me u se futhumale ho 500 ℃ ka khase ea chlorine bakeng sa ho bala.Bokella sehlahisoa u sebelisa sefi ka mocheso oa kamore.Ha ho nahanoa ka sublimation ea zirconium tetrachloride ho 331 ℃, tube e telele ea 600mm e ka sebelisoa ho e khutlisetsa ka har'a khase ea hydrogen ho 300-350 ℃ ho tlosa li-oxide le ferric chloride ka zirconium chloride.
4. Tšusumetso tikolohong
Likotsi tsa bophelo bo botle
Tsela ea ho hlasela: ho hema, ho kenngoa, ho kopana le letlalo.
Kotsi ea bophelo bo botle: Ho hema ho ka baka ho teneha ha phefumoloho, u se ke ua metsa.E na le bohale bo matla mme e ka baka ho chesa ha letlalo le ho senya mahlo.Ho sebelisa molomo ho ka baka ho chesa ha molomo le 'metso, ho nyekeloa ke pelo, ho hlatsa, mantle a nang le metsi, mantle a nang le mali, ho oa le ho ferekana.
Liphello tse sa foleng: E baka granuloma ea letlalo.Ho teneha ha bobebe ho phefumoloho.
Toxicology le Tikoloho
Chefo e matla: LD501688mg/kg (tsamaiso ea molomo ho likhoto);665mg/kg (molomo oa toeba)
Litšobotsi tse kotsi: Ha li le tlas'a mocheso kapa metsi, lia bola ebe li ntša mocheso, 'me li ntša mosi o chefo le o senyang.
Ho chesa (ho bola) sehlahisoa: hydrogen chloride.
Mokhoa oa ho hlahloba laboratori: Plasma spectroscopy (mokhoa oa NIOSH 7300)
Boikemisetso moeeng: bokella sampole ka sefe, e qhale ka asiti, ebe u e lekanya ka spectroscopy ea ho monya athomo.
Maemo a Tikoloho: Occupational Safety and Health Administration (1974), Air Time Weighted Average 5.
Karabo ea tšohanyetso ea ho lutla
Arola sebaka seo ho lutlang ho sona, beha matšoao a temoso ho e potoloha, 'me u khothaletse basebetsi ba ts'ohanyetso ho roala maske a khase le liaparo tse sireletsang lik'hemik'hale.U se ke ua kopana ka ho toba le lintho tse lutlang, qoba lerole, u li fiele ka hloko, lokisetsa tharollo ea metsi kapa asiti e ka bang 5%, butle-butle eketsa metsi a ammonia ho fihlela pula e hlaha, ebe u e lahla.U ka boela ua hlatsoa ka metsi a mangata, 'me ua hlapolla metsi a hlatsoang ka har'a tsamaiso ea metsi a litšila.Haeba ho na le palo e kholo ea ho lutla, e tlose tlas'a tataiso ea basebetsi ba theknoloji.Mokhoa oa ho lahla litšila: Kopanya litšila le sodium bicarbonate, fafatsa ka metsi a ammonia, 'me u kenye leqhoa le pshatlehileng.Ka mor'a hore karabelo e khaotse, hlatsoa ka metsi ka har'a likhoerekhoere.
Mehato ea ts'ireletso
Tšireletso ea ho hema: Ha u pepesehile lerōleng, mask a khase a lokela ho apesoa.Apara sesebelisoa sa ho phefumoloha se ikemetseng ha ho hlokahala.
Tšireletso ea mahlo: Roala likhalase tsa tšireletso tsa lik'hemik'hale.
Liaparo tse sireletsang: Apara liaparo tsa mosebetsi (tse entsoeng ka thepa e thibelang ho bola).
Tšireletso ea letsoho: Apara liatlana tsa rabara.
Tse ling: Ka mor'a mosebetsi, hlapa 'me u fetole liaparo.Boloka liaparo tse silafalitsoeng ke chefo ka thoko 'me u li sebelise hape ka mor'a ho li hlatsoa.Boloka mekhoa e metle ea bohloeki.
Mehato ea thuso ea pele
Ho ama letlalo: Hlatsoa hang-hang ka metsi bonyane metsotso e 15.Haeba ho chesoa, batla phekolo ea meriana.
Ho shebana le mahlo: Phahamisa lintši hang-hang 'me u hlatsoe ka metsi a phallang kapa saline ea 'mele bonyane metsotso e 15.
Inhalation: Tlosa ka potlako sebakeng seo u e ise sebakeng se nang le moea o hloekileng.Boloka tsela e sa sitisoeng ea ho hema.Phefumoloha ka maiketsetso ha ho hlokahala.Batla thuso ea bongaka.
Ho noa: Ha mokuli a tsohile, hlatsoa molomo oa hae hang-hang, u se ke ua etsa hore a hlatse, 'me u noe lebese kapa bosoeu ba mahe.Batla thuso ea bongaka.
Mokhoa oa ho tima mollo: foam, carbon dioxide, lehlabathe, phofo e omileng.
5.Mokhoa oa ho boloka
Boloka sebakeng sa polokelo se pholileng, se omeletseng, se nang le moea o motle.Qoba hole le litlhase le mehloli ea mocheso.Sephutheloana se tlameha ho koaloa le ho sireletsoa ho tloha mongobo.E lokela ho bolokoa ka thoko ho li-acids, amines, alcohols, ester, joalo-joalo, 'me u qobe ho kopanya polokelo.Sebaka sa polokelo se lokela ho hlomelloa ka lisebelisoa tse loketseng ho ba le ho lutla.
6 k'hemistri ea khomphutha Ho hlophisa data
1. Reference value for hydrophobic parameter calculation (XlogP): Ha ho letho
2. Palo ea bafani ba bond ea haedrojene: 0
3. Palo ea li-receptor tsa hydrogen bond: 0
4. Palo ea bond ea lik'hemik'hale tse rotatable: 0
5. Palo ea li-tautomers: Ha ho letho
6. Polarity ea holim'a molek'hule ea holimo: 0
7. Palo ea liathomo tse boima: 5
8. Tefiso ea bokaholimo: 0
9. Ho rarahana: 19.1
10. Palo ea liathomo tsa Isotope: 0
11. Fumana palo ea litsi tsa sebopeho sa athomo: 0
12. Palo ea litsi tse sa tsitsang tsa kaho ea athomo: 0
13. Fumana palo ea litsi tsa stereo tsa lik'hemik'hale: 0
14. Palo ea li-chemical bond stereocenters tse sa tsitsang: 0
15. Palo ea li-covalent bond units: 1
Nako ea poso: May-25-2023